You would add a DHCP Option 6 to the LAN DHCP config in the LuCI web GUI:
Or in /etc/config/dhcp
config dhcp 'lan'
option interface 'lan'
option start '100'
option limit '150'
option leasetime '12h'
option dhcpv6 'server'
option ra 'server'
option ra_management '1'
list dhcp_option '6,8.8.8.8,8.8.4.4'