Two wifi AP : with and without Openvpn connecion

Okay, I seemed fixed this. So I will put my solution here if someone will need it.
I followed every step above @psherman sir suggested. After that:

First I disabled default route in openvpn config (Docs):

pull-filter ignore "redirect-gateway"

Then I followed This solution

These are changes according to that (as Images because I don't know how to do this in cli):

LUCI Images

Configs
root@OpenWrt:~# ubus call system board
{
        "kernel": "5.10.176",
        "hostname": "OpenWrt",
        "system": "MediaTek MT7621 ver:1 eco:3",
        "model": "Xiaomi Mi Router 4A Gigabit Edition",
        "board_name": "xiaomi,mi-router-4a-gigabit",
        "rootfs_type": "squashfs",
        "release": {
                "distribution": "OpenWrt",
                "version": "22.03.5",
                "revision": "r20134-5f15225c1e",
                "target": "ramips/mt7621",
                "description": "OpenWrt 22.03.5 r20134-5f15225c1e"
        }
}
root@OpenWrt:~# uci export dhcp
package dhcp

config dnsmasq
        option domainneeded '1'
        option boguspriv '1'
        option filterwin2k '0'
        option localise_queries '1'
        option rebind_protection '1'
        option rebind_localhost '1'
        option local '/lan/'
        option domain 'lan'
        option expandhosts '1'
        option nonegcache '0'
        option authoritative '1'
        option readethers '1'
        option leasefile '/tmp/dhcp.leases'
        option resolvfile '/tmp/resolv.conf.d/resolv.conf.auto'
        option nonwildcard '1'
        option localservice '1'
        option ednspacket_max '1232'

config dhcp 'lan'
        option interface 'lan'
        option start '100'
        option limit '150'
        option leasetime '12h'
        option dhcpv4 'server'
        option dhcpv6 'server'
        option ra 'server'
        list ra_flags 'managed-config'
        list ra_flags 'other-config'
        option ra_default '1'

config odhcpd 'odhcpd'
        option maindhcp '0'
        option leasefile '/tmp/hosts/odhcpd'
        option leasetrigger '/usr/sbin/odhcpd-update'
        option loglevel '4'

config dhcp 'NoVpn'
        option interface 'NoVpn'
        option start '100'
        option limit '150'
        option leasetime '12h'
        option dhcpv4 'server'

root@OpenWrt:~# uci export firewall
package firewall

config defaults
        option input 'ACCEPT'
        option output 'ACCEPT'
        option synflood_protect '1'
        option forward 'ACCEPT'

config zone
        option name 'lan'
        option input 'ACCEPT'
        option output 'ACCEPT'
        option forward 'ACCEPT'
        list network 'lan'

config zone
        option name 'wan'
        option output 'ACCEPT'
        option masq '1'
        option mtu_fix '1'
        option input 'ACCEPT'
        option forward 'ACCEPT'
        list network 'wwan'
        list network 'wwan6'

config rule
        option name 'Allow-DHCP-Renew'
        option src 'wan'
        option proto 'udp'
        option dest_port '68'
        option target 'ACCEPT'
        option family 'ipv4'

config rule
        option name 'Allow-Ping'
        option src 'wan'
        option proto 'icmp'
        option icmp_type 'echo-request'
        option family 'ipv4'
        option target 'ACCEPT'

config rule
        option name 'Allow-IGMP'
        option src 'wan'
        option proto 'igmp'
        option family 'ipv4'
        option target 'ACCEPT'

config rule
        option name 'Allow-DHCPv6'
        option src 'wan'
        option proto 'udp'
        option dest_port '546'
        option family 'ipv6'
        option target 'ACCEPT'

config rule
        option name 'Allow-MLD'
        option src 'wan'
        option proto 'icmp'
        option src_ip 'fe80::/10'
        list icmp_type '130/0'
        list icmp_type '131/0'
        list icmp_type '132/0'
        list icmp_type '143/0'
        option family 'ipv6'
        option target 'ACCEPT'

config rule
        option name 'Allow-ICMPv6-Input'
        option src 'wan'
        option proto 'icmp'
        list icmp_type 'echo-request'
        list icmp_type 'echo-reply'
        list icmp_type 'destination-unreachable'
        list icmp_type 'packet-too-big'
        list icmp_type 'time-exceeded'
        list icmp_type 'bad-header'
        list icmp_type 'unknown-header-type'
        list icmp_type 'router-solicitation'
        list icmp_type 'neighbour-solicitation'
        list icmp_type 'router-advertisement'
        list icmp_type 'neighbour-advertisement'
        option limit '1000/sec'
        option family 'ipv6'
        option target 'ACCEPT'

config rule
        option name 'Allow-ICMPv6-Forward'
        option src 'wan'
        option dest '*'
        option proto 'icmp'
        list icmp_type 'echo-request'
        list icmp_type 'echo-reply'
        list icmp_type 'destination-unreachable'
        list icmp_type 'packet-too-big'
        list icmp_type 'time-exceeded'
        list icmp_type 'bad-header'
        list icmp_type 'unknown-header-type'
        option limit '1000/sec'
        option family 'ipv6'
        option target 'ACCEPT'

config rule
        option name 'Allow-IPSec-ESP'
        option src 'wan'
        option dest 'lan'
        option proto 'esp'
        option target 'ACCEPT'

config rule
        option name 'Allow-ISAKMP'
        option src 'wan'
        option dest 'lan'
        option dest_port '500'
        option proto 'udp'
        option target 'ACCEPT'

config zone
        option name 'ovpn'
        option input 'ACCEPT'
        option output 'ACCEPT'
        option masq '1'
        option mtu_fix '1'
        option forward 'ACCEPT'
        list network 'opvpn'

config forwarding
        option src 'lan'
        option dest 'ovpn'

config include 'pbr'
        option fw4_compatible '1'
        option type 'script'
        option path '/usr/share/pbr/pbr.firewall.include'

config zone
        option name 'novpn'
        option input 'ACCEPT'
        option output 'ACCEPT'
        option forward 'ACCEPT'
        list network 'NoVpn'

config forwarding
        option src 'novpn'
        option dest 'wan'

root@OpenWrt:~# uci export network
package network

config interface 'loopback'
        option device 'lo'
        option proto 'static'
        option ipaddr '127.0.0.1'
        option netmask '255.0.0.0'

config globals 'globals'
        option packet_steering '1'
        option ula_prefix 'fd4e:424f:5ca4::/48'

config device
        option name 'br-lan'
        option type 'bridge'
        list ports 'lan1'
        list ports 'lan2'

config interface 'lan'
        option device 'br-lan'
        option proto 'static'
        option ip6assign '60'
        option ipaddr '10.0.0.1'
        option netmask '255.255.255.0'

config interface 'wwan'
        option proto 'dhcp'

config interface 'opvpn'
        option proto 'none'
        option device 'tun0'

config device
        option name 'br-novpn'
        option type 'bridge'

config interface 'NoVpn'
        option proto 'static'
        option ipaddr '10.0.5.1'
        option netmask '255.255.255.0'
        option device 'br-novpn'

root@OpenWrt:~# uci export pbr
package pbr

config pbr 'config'
        option verbosity '2'
        option strict_enforcement '1'
        option resolver_set 'none'
        option ipv6_enabled '0'
        list ignored_interface 'vpnserver'
        list ignored_interface 'wgserver'
        option boot_timeout '30'
        option rule_create_option 'add'
        option procd_reload_delay '1'
        option webui_show_ignore_target '0'
        list webui_supported_protocol 'all'
        list webui_supported_protocol 'tcp'
        list webui_supported_protocol 'udp'
        list webui_supported_protocol 'tcp udp'
        list webui_supported_protocol 'icmp'
        option enabled '1'

config include
        option path '/usr/share/pbr/pbr.user.aws'
        option enabled '0'

config include
        option path '/usr/share/pbr/pbr.user.netflix'
        option enabled '0'

config policy
        option name 'Plex/Emby Local Server'
        option interface 'wan'
        option src_port '8096 8920 32400'
        option enabled '0'

config policy
        option name 'Plex/Emby Remote Servers'
        option interface 'wan'
        option dest_addr 'plex.tv my.plexapp.com emby.media app.emby.media tv.emby.media'
        option enabled '0'

config policy
        option name 'no_vpn'
        option src_addr '10.0.5.1/24'
        option dest_addr '!10.0.5.1/24'
        option interface 'wwan'

config policy
        option name 'vpn'
        option src_addr '10.0.0.1/24'
        option dest_addr '!10.0.0.1/24'
        option interface 'opvpn'

root@OpenWrt:~# uci export wireless
package wireless

config wifi-device 'radio0'
        option type 'mac80211'
        option path '1e140000.pcie/pci0000:00/0000:00:01.0/0000:02:00.0'
        option channel '1'
        option band '2g'
        option htmode 'HT20'
        option cell_density '0'

config wifi-iface 'default_radio0'
        option device 'radio0'
        option network 'lan'
        option mode 'ap'
        option ssid 'OpenWrt'
        option encryption 'psk-mixed'
        option key '1234567890'

config wifi-device 'radio1'
        option type 'mac80211'
        option path '1e140000.pcie/pci0000:00/0000:00:00.0/0000:01:00.0'
        option channel '36'
        option band '5g'
        option htmode 'VHT80'
        option cell_density '0'

config wifi-iface 'wifinet4'
        option device 'radio1'
        option mode 'sta'
        option ssid 'connecting..'
        option encryption 'psk2'
        option key '1234567890'
        option network 'wwan wwan6'

config wifi-iface 'wifinet2'
        option device 'radio0'
        option mode 'ap'
        option ssid 'OpenWrtNoVpn'
        option encryption 'none'
        option network 'NoVpn'

I haven't tested everyting like DNS leaking and all.
Thanks everone for helping me.