Some info is missing: What do you want to achieve?
I assume, you want to limit the users traffic to "...Total-Octets" and to limit the logged-in period (duration of time, user can be online). Correct ?
Second, where/ how do you set "Expire-After..." ?
However, this is no openwrt issue, but freeradius. And sounds like a commercial hotspot system.
i use Openwrt with chillispot and freeradius. I have tickets with time limit or with traffic limit. Expire-After is in the mysql database, do you mean this?
Since ChilliSpot-Max-Total-Octets is a vendor specific attribute, the chilli dictionary must be installed on your RADIUS server for this to work. Then you should sniff the network to see if it is being sent correctly to the hotspot as the access reply.