I think it also depends on how big prefix you have from your ISP, and if the ISP's router can do prefix delegation.
Unfortunately some ISP for inconceivable reason assign only /64 prefix. If that's the case then prefix delegation won't work. This means your setup connected the lan from isp router to the wan of Openwrt would not work.
You may consider connecting OpenWrt directly without the ISP's router, if possible.
If that's not possible (e.g. it's DOCSIS (coax cable) router, fibre optic), you may try switching the ISP router to a "bridge mode", if the router supports that.
IMO the setup connected the lan from isp router to the wan of Openwrt is not best setup even if it worked, because it introduces yet another NAT on IPv4 which means that if you need port forwarding you would need to set in in two routers. It's really for best to completely replace ISP's router, or at least switch it to bridge mode. In my opinion.
wrt screenshots, as @frollic said it's for client, you do not want to set that wan6 interface, if anything you may want to set it up on lan interface (but I think RA/DHCPv6 should be enabled by default on lan).
Could you post (redacted) screenshot of you "interfaces" page (cgi-bin/luci/admin/network/network)?