I found a solution through the command line, but not through the LEDE GUI:
- connect to router by SSH client (PuTTY for example)
- in command prompt (under 'root' user) type:
uci add_list dhcp.@dnsmasq[0].dhcp_boot='pxelinux.0,<name of external tftp pxe server>,<IP of external tftp pxe server'
uci commit dhcp