If the powerline is already paired then no there is nothing to do. You can however change that using plc-tool (haven't used it myself).
Don't instlal any snapshot. As far as I know you can install the factory image directly from the web interface. Nothing else to do.
Once you install it maybe add luci. The space is already reduced on the image (around 1mb left after initial install). You can then manage your wireless using Luci.
The OpenWRT snapshot images are well tested by now, see the wiki for more info.
Like most consumer powerline devices, The TP-Link PLC devices come setup out of the box using the default Network Membership Key based on the "HomePlugAV" password. You can set a new NMK in the TP-Link stock firmware before switching over to OpenWRT.
Or, once your running OpenWRT, you can change it easily with this:
For the other powerline adaptors you can use the TPPLC windows utility. You might also be able to use plctool for those too via the Ethernet side, but its trickier and depends on the device.