Thank you for taking the time to answer!
By this do you mean replace the isp router?
Exactly this.
So does your isp provide an incoming ethernet feed?
They do (or I have BADLY misunderstood what I'm recieving)
Alternatively, can your isp router be configured in a modem-only bridge mode?
It can be, but my desire is to eliminate a piece of hardware taking up space, so doing so would fail to provide the benefit I'm looking for.
Do you know how you would configure a single mt300n-v2 to work with PPPoE?
In theory yes, in practice no. My ISP provides OpenWRT-specific instructions, which I can follow, but at this point in time I have not tried to do so.
mt300n-v2 is very capable, to be honest, it is getting pretty old and outdated
I bought the mt300n-v2 to provide me with cheap hardware to test a proof of concept while still being able to easily go back to my existing set-up in the case of issues - if I can assure myself I can get everything I want working under OpenWRT, I will commit to buying hardware more suitable to my needs.
With the mt300n-v2 I have already observed that I can't have clients connect to both of the SSIDs I'm advertising without crashing out the connections - from searching online, this appears to be a limitation of the wireless chip in the device (although I would welcome being told it is something I can overcome in software).
Even with the comparatively 'small' mt300n-v2s, my testing of the two-node mesh plugged into the ISP's router has been entirely satisfactory, supplying bitrates that meet my needs - although my final set-up will probably be less performant as I'll need to put a wireless backhaul link into the topology (currently, the two mt300n-v2s have access to a wired interconnect). The only unsatisfactory thing is, as mentioned above, is being unable to connect to both SSIDs at once (well, and not knowing how to remove my ISP's router from the set up ... but it looks like I'm in the right place for the help I need with that!).