So I got it working. Take everything with a grain of salt, there might be some don'ts in my configuration, however....IT WORKS! 
Without fully understanding the difference it makes to have eth0.2000 and eth1.2000 (basically, what would you do to puth eth0 and eth1 on the same vlan.....tag both of them 2000, right?) I created a separate vlan for the second modem because I decided that its indeed a separate network and not just a third static ip in the old modems network. Whatever.
Then, because of mwan3 and because of the new modem (modem_mob) only getting a /64 prefix I had to change everything to ipv6 masquerading / nat66.
This is the shortened config / network:
/etc/config/network
network.globals=globals
network.globals.ula_prefix=''
network.@switch[0]=switch
network.@switch[0].name='switch0'
network.@switch[0].reset='1'
network.@switch[0].enable_vlan='1'
network.@switch_vlan[0]=switch_vlan
network.@switch_vlan[0].device='switch0'
network.@switch_vlan[0].vlan='1'
network.@switch_vlan[0].description='lan'
network.@switch_vlan[0].ports='4t 6t'
network.@switch_vlan[0].vid='10'
network.@switch_vlan[1]=switch_vlan
network.@switch_vlan[1].device='switch0'
network.@switch_vlan[1].vlan='2'
network.@switch_vlan[1].ports='0t 5'
network.@switch_vlan[1].description='wan'
network.@switch_vlan[1].vid='2000'
network.@switch_vlan[9]=switch_vlan
network.@switch_vlan[9].device='switch0'
network.@switch_vlan[9].vlan='10'
network.@switch_vlan[9].ports='3 6t'
network.@switch_vlan[9].vid='2010'
network.@switch_vlan[9].description='wan_mobile'
network.loopback=interface
network.loopback.proto='static'
network.loopback.ipaddr='127.0.0.1'
network.loopback.netmask='255.0.0.0'
network.loopback.device='lo'
network.br_lan=device
network.br_lan.name='br-lan'
network.br_lan.type='bridge'
network.br_lan.ports='eth1.10'
network.lan=interface
network.lan.proto='static'
network.lan.ipaddr='192.168.1.1'
network.lan.netmask='255.255.255.0'
network.lan.ip6assign='60'
network.lan.device='br-lan'
network.lan.ip6hint='10'
network.iso_modem=interface
network.iso_modem.proto='static'
network.iso_modem.netmask='255.255.255.0'
network.iso_modem.ipaddr='192.168.200.1'
network.iso_modem.ifname='eth0.2000'
network.iso_modem.device='eth0.2000'
network.iso_modem_mob=interface
network.iso_modem_mob.proto='static'
network.iso_modem_mob.device='eth1.2010'
network.iso_modem_mob.ipaddr='192.168.201.1'
network.iso_modem_mob.netmask='255.255.255.0'
network.wan=interface
network.wan.proto='pppoe'
network.wan.ipv6='1'
network.wan.peerdns='0'
network.wan.dns='9.9.9.9' '149.112.112.112'
network.wan.username=''
network.wan.password=''
network.wan.device='eth0.2000'
network.wan.metric='10'
network.wan_6=interface
network.wan_6.proto='dhcpv6'
network.wan_6.device='pppoe-wan'
network.wan_6.reqaddress='try'
network.wan_6.reqprefix='auto'
network.wan_6.peerdns='0'
network.wan_6.dns='2620:fe::fe' '2620:fe::9'
network.wan_6.sourcefilter='0'
network.wan_6.delegate='0'
network.wan_6.metric='10'
network.wan_mob=interface
network.wan_mob.proto='dhcp'
network.wan_mob.device='eth1.2010'
network.wan_mob.metric='20'
network.wan_mob.peerdns='0'
network.wan_mob.dns='9.9.9.9' '149.112.112.112'
network.wan_mob_6=interface
network.wan_mob_6.proto='dhcpv6'
network.wan_mob_6.device='eth1.2010'
network.wan_mob_6.reqaddress='try'
network.wan_mob_6.reqprefix='auto'
network.wan_mob_6.peerdns='0'
network.wan_mob_6.metric='20'
network.wan_mob_6.dns='2620:fe::fe' '2620:fe::9'
network.wan_mob_6.delegate='0'
network.wan_mob_6.sourcefilter='0'
And as you can see, what I am doing is having a corresponding interface on the wan device for management purposes with a static ip. So iso_modem_mob is for accessing wan_mob modem ui and iso_modem is for accessinc wan modem ui.